Abstract

The kinetics of the Mn(II)/Mn(Hg) electrode process have been studied in DMF and DMF+water mixtures. Diffusion coefficients, formal potentials and charge-transfer rate constants were determined. The influence of NaClO 4 concentration on the kinetic parameters in selected DMF mixtures with water was studied. The kinetic desolvation step preceding the charge transfer was sought in DMF at −30°C. Two models of the electrode process in mixtures of water with solvents more basic than water are discussed.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.