Abstract
Excess thermodynamic functions (free energies, enthalpies and entropies of mixing) have been obtained from measurements of vapour pressures, together with excess volumes of mixing, for mixtures of hexafluorobenzene with carbon tetrachloride and with perfluoromethyl-cyclohexane (tetradecafluoromethylcyclohexane). Deviations from thermodynamic ideality are large, although the systems are completely miscible. Critical temperatures of the mixtures are also reported. A correlation between the data, anticipated from a simple model for mixtures of asymmetric molecules, does not obtain.
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