Abstract
Abstract The microwave spectrum of (Z)-(acrylaldehyde oxime) was observed in the frequency region from 10 to 40 GHz. Several a-type R-branch transitions in the ground vibrational state were identified and the rotational constants in MHz were determined to be A=17430.7(35), B=3022.514(15), and C=2576.504(16). The conformation of (Z)-(acrylaldehyde oxime) has been plausibly deduced to be the s-trans Z-form from the rotational constants experimentally determined. The angle of C–C=N is discussed.
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