Abstract
The rotational Zeeman effect has been investigated for four different isotopic species of SiH3NCS. From the observed g-values we have determined the sign of the electric dipole-moment in SiH3NCS to be ⊕H3SiNCS⊖. Thus the previous choice of sign which had been based on the results of a quantum chemical CNDO/2 calculation had to be revised. For the master isotope g⊥, g|| and (x⊥-X||) have been determined and were used to calculate the molecular electric quadrupole moment, the paramagnetic and diamagnetic susceptibilities and the second moments of the electronic charge distribution
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