Abstract

The microwave spectra of four deuterated species of cyclopropyl carbinol have been studied. The rotational constants A, B, and C (in MHz) are: C3H5CHaDbOH, 11 742.86, 3205.17, 2830.41; C3H5CDaHbOH, 11 853.44, 3188.10, 2878.28; C3H5CHaDbOD, 11 321.30, 3145.87, 2762.23; C3H5CDaHbOD, 11 433.85, 3129.30, 2809.81. The measured dipole moments of C3H5CHaDbOH and C3H5CHaDbOD are, respectively, 1.91 and 1.873 D. This confirms the essential details of the conformation proposed in an earlier paper.

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