The microstructure and mechanical performance optimization of a new Fe-Ni-based superalloy for Gen IV nuclear reactor: The critical role of Nb alloying strategy

Abstract

The effects of Nb alloying on microstructural evolution and mechanical performance of a newly developed solid-solution strengthened Fe-Ni-based superalloy, considered as the candidate material for high-temperature components manufacturing in fourth Generation (Gen IV) advanced nuclear reactor, were systematically investigated. The results show that the increase in the Nb content obviously increased the volume fraction and average size of MC carbides, and the MC carbides more preferentially distributed at grain boundaries. The average grain size and low Σ coincident site lattice (CSL) boundary exhibited a gradually decreased trend with increasing Nb content. Meanwhile, the thermal stability (grain size and grain boundary precipitation) of the alloy can be improved notably via Nb alloying. The tensile strength of Nb-alloyed alloys at 750 °C was enhanced significantly compared to that of Nb-free alloy, mainly due to the synergistic effect of solid-solution strengthening and fine grain strengthening. It was impressive that the variation of Nb content had no obvious influence on the yield strength, but gradually decreased the ultimate tensile strength. The detrimental effects of the decrease in Σ3 boundaries and intergranular precipitates were assumed to restrict the strengthening factors. The ductility of Nb-alloyed alloys decreased remarkably due to the changed dominant deformation mechanism from planar slip to wavy slip; however, it showed an increasing trend in high Nb-content alloys due to the occurrence of dynamic recrystallization and grain rotation. The present work establishes Nb alloying as an effective method to optimize the microstructure and mechanical properties of solid-solution strengthened Fe-Ni-based superalloys, and the appropriate Nb content is recommended to be controlled below 0.5 wt% for this alloy.