Abstract

In this study, the high strain rate deformation behavior and the microstructure evolution of Zr-Cu-Al-Ni metallic glasses under various strain rates were investigated. The influence of strain and strain rate on the mechanical properties and fracture behavior, as well as microstructural properties was also investigated. Before mechanical testing, the structure and thermal stability of the Zr-Cu-Al-Ni metallic glasses were studied with X-ray diffraction (XRD) and differential scanning calorimeter. The mechanical property experiments and microstructural observations of Zr-Cu-Al-Ni metallic glasses under different strain rates ranging from 10−3 to 5.1 × 103 s−1 and at temperatures of 25 °C were investigated using compressive split-Hopkinson bar (SHPB) and an MTS tester. An in situ transmission electron microscope (TEM) nanoindenter was used to carry out compression tests and investigate the deformation behavior arising at nanopillars of the Zr-based metallic glass. The formation and interaction of shear band during the plastic deformation were investigated. Moreover, it was clearly apparent that the mechanical strength and ductility could be enhanced by impeding the penetration of shear bands with reinforced particles.

Highlights

  • Bulk metallic glass (BMG) and its composites (BMGC) are of interest due to their unique mechanical, physical, and chemical properties, such as amorphous microstructure, ultra-high strength, large limit of elastic deformation, and excellent corrosion resistance [1,2,3,4,5]

  • Compression, or tension tests, the formation of shear bands leads to brittle fractures along the shear planes, and the resulting lack of ductility greatly limits the application of BMG

  • This study used an in situ transmission electron microscope (TEM) nanoindenter to carry out compression tests and investigate the related deformation behavior arising at nanopillars of the Zr-based metallic glass

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Summary

Introduction

Bulk metallic glass (BMG) and its composites (BMGC) are of interest due to their unique mechanical, physical, and chemical properties, such as amorphous microstructure, ultra-high strength, large limit of elastic deformation, and excellent corrosion resistance [1,2,3,4,5]. Compression, or tension tests, the formation of shear bands leads to brittle fractures along the shear planes, and the resulting lack of ductility greatly limits the application of BMG. Reinforcements such as refractory metals, fibers, and ceramic particles have been added into BMG matrices to enhance their ductility [8,9,10,11]. This study used an in situ transmission electron microscope (TEM) nanoindenter to carry out compression tests and investigate the related deformation behavior This study used an in situ transmission electron microscope (TEM) nanoindenter to carry out compression tests and investigate the related deformation behavior (ex. shear banding and buckling deformations) arising at nanopillars of the Zr-based metallic glass

Material Preparation and Experimental Procedure
Structure Analysis of Zr-Based Metallic Glass
Stress-Strain Curve and Strain Rate Effect
Fracture Surface Observations
Microstructural Evolution by Using in situ TEM Compression
Conclusions
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