Abstract

All-electron, ab initio molecular orbital calculations have been performed on electronic states of CH 4 2+ using perturbative configuration interaction procedures and large sets of Gaussian basis functions with a view to attempting reconciliation between contemporary quantum-chemical information and different sets of experimen-tal data from charge-stripping, threshold photoionization, and double-charge-transfer mass spectrometry. Metastable electronic states of CH 4 2+ are predicted for D 4h and D 2d symmetries, with charge-stripping experiments likely to populate spin singles of the former symmetry. Investigation of the dissociation of CH 4 2+ (D 4h ) to CH 3 + (D 3h )+ H + along the C 2v symmetry pathway indicates that theoretical and experimental data on metastable states of this dication are in accord only if non-Frank-Condon transitions are postulated.

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