Abstract
The first step in the proposed mechanism is the formation of an osazone–Cu(II) complex that undergoes a one-electron shift from the nitrogen of the ligand to the metal in the complex which is reduced to Cu(I). This complex decomposes with the liberation of Cu(I) +, a ligand radical which undergoes a set of one-electron shifts to form a phenylimine radical (Ph–NH) and the triazole. The Cu(I) + produced is converted to Cu(II) 2+ and Cu 0 by disproportionation.
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