Abstract
The isothermal luminescence of γ-irradiated 3-methylpentane and methylcyclohexane glasses in the presence of naphthalene (10 −4−10 −1 mol dm −3) was investigated at 77 K. The isothermal luminescence is explained by the tunnelling mechanism involving electrons and cations in the range of low solute concentrations ( ca. ≤7 × 10 −3 mol dm −3) and solute anions and cations in the range of high solute concentrations (up to 10 −1 mol dm −3). Evidence is presented that the β-coefficient in Bagdasar'yan equation is related to the distribution of recombining ion pairs.
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