The Mechanism for the Barrier of Lunar Regolith on the Migration of Water Molecules

Abstract

AbstractThis paper reports the study of potential water retention mechanisms based on the migration process of water molecules in the lunar regolith. First, we propose innovative definitions for the adsorption barrier coefficient, the collision barrier coefficient, and the total barrier coefficient for water molecule migration in the lunar regolith. Second, we derive an equation that relates the different barrier coefficients. Finally, we develop an equation for the diffusion coefficient of water in the regolith. The results are as follows. The collision barrier coefficient is a function of the soil layer porosity and pore number density and increases with increasing pore number density and decreasing porosity. The adsorption barrier coefficient depends on the soil temperature, adsorption heat, porosity, and pore number density and decreases sharply with increasing temperature. The adsorptive capacity of lunar soil to adsorb water molecules increases with increasing the adsorption barrier coefficient. For soil layers with a lower temperature, adsorption plays a more important role than collision in hindering the migration of molecules in the regolith. The total barrier coefficient increases with decreasing temperature, increasing adsorption heat, decreasing porosity, and increasing pore number density. Our results suggest that the water loss rate is inversely proportional to the total barrier coefficient. The water loss rate decreases with decreasing soil temperature, increasing adsorption heat, decreasing porosity, and increasing pore number density. Namely, water is more likely to be retained in areas where the regolith has a low temperature, large adsorption heat, and both low porosity and large pore number density.