The mechanical properties of Al3Sc single crystal investigated by nanoindentation using Hertzian elasticity theory method and Oliver-Pharr method

Abstract

The crystal structure, orientation, reduced modulus, and hardness of Al3Sc single crystal were studied using X-ray diffraction (XRD), electron backscatter diffraction (EBSD) and nanoindentation techniques, combined with Hertzian elastic theory method (Hertz) and Oliver-Pharr method (O&P). Millimeter-sized Al3Sc single crystals were prepared using quasi-equilibrium solidification of hypereutectic Al-15(wt %) Sc alloy. The XRD results showed that the samples were composed of L12-Al3Sc and Al phases. The EBSD and nanoindentation results showed that for five Al3Sc single crystals with different orientations, the reduced moduli measured by Hertz method were 146.6 ± 0.4–148.3 ± 0.2 GPa; while measured by O&P method they were 147 ± 2–150 ± 3 GPa. The corresponding hardnesses were varied between 3.8 ± 0.1 and 3.9 ± 0.1 GPa. The Poisson's ratio and elastic constants were determined through iterative calculation based on the relationship between the reduced modulus and Young’s modulus at various orientations. The polycrystal elastic properties, bulk modulus, shear modulus and Young's modulus, were determined. The elastic constants c11, c12, and c44 were 179.2 ± 0.4, 44.1 ± 0.1, and 68.3 ± 0.3 GPa, respectively; the Poisson's ratio was 0.196 ± 0.001. The Young's modulus of five Al3Sc single crystals oriented in different directions was in the narrow range 161–164 GPa. The anisotropy factor of Al3Sc crystal was 1.011 ± 0.002, confirming that it is elastically isotropic. These results provide fundamental information for the research and development of the Al3Sc intermetallic compound and related alloys in future.