Abstract
AbstractThe mass spectral behavior of trans‐1‐arylsulfonyl‐2‐arylsulfenyl‐propenes, trans‐1‐arylsulfonyl‐2‐arylsulfinyl‐propenes and trans‐1, 2‐(arylsulfonyl)‐propenes was examined. A Smiles type rearrangement was present in the sulfonyl‐sulfides, but was completely absent in the trans‐1‐arylsulfonyl‐2‐arylsulfinyl‐propenes and trans‐1, 2‐(arylsulfonyl)‐propenes. Vinyl migration to the sulfone oxygen predominates over aryl migration in all of the compounds studied. The mass spectra of the cis and trans isomers of 1‐p‐tolylsulfenyl‐2‐p′‐tolysulfonyl‐propene and 1, 2‐(p‐tolylsulfonyl)‐propene are also described.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
