Abstract

Microwave induced delayed phosphorescence (MIDP) measurements have been performed in the 00 bands of the phosphorescence spectrum of benzene dissolved in two phases of cyclohexane. From the relative radiative rates for decay of the three zero-field levels it is concluded that on the average the symmetry of the electronic structure is lower than D 2h. In the monoclinic low temperature stable phase of cyclohexane (phase II) the structure is approximately antiquinoidal, and in the metastable phase III it is approximately quinoidal.

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