Abstract
We report the low temperature magnetic behavior of a complex with nominal formula “Mn(OAc)(OBz)(μ-O) 0.1”. It is presumed that the phase responsible for the interesting magnetic phenomena is related to {Mn 5(OAc) 4(OBz) 6} ∞ – a recently reported complex comprised of two dimensional sheets of Mn 12 loops arranged in a honeycomb-like fashion via carboxylate bridging in the plane. Temperature and field dependent magnetic studies show exchange transitions between 1.7 and 12 K which are similar to those found in other Mn carboxylate complexes. The point of interest we wish to explore in this paper, that differs from similar manganese carboxylate-based complexes, is the rather strong two-dimensional antiferromagnetic exchange and the possible role of interplanar exchange on ordering.
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