Abstract

The low frequency IR and Raman spectra of Cd(DH4)X2 (X=Cl, Br;DH=dithiooxamide) have been discussed. On the basis of the cadmium isotope and H-D shift as well as chlorine-bromine substitution a band assignment in the region 500–33 cm−1 has been made. A polymeric structure of Cd(DH4)X2 involving both dithiooxamide and halogen bridges with D4h symmetry of the cadmium environment is assumed.

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