Abstract

Abstract— A new synthetic approach for the preparation of various mesomorphic chiral and non‐chiral derivatives of cyclohexene, cyclohexane, phenylcyclohexane, or biphenyl with different combinations of cyclic, bridge, terminal fragments and lateral substituents is proposed and realized. Both nematic and smectic liquid‐crystalline compounds were prepared by the transformations of the corresponding 3,6‐disubstituted cyclohex‐2‐enones.

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