The Line of Ideal Isothermal Compressibility.

Abstract

We have considered the line along which the values of the isothermal compressibility of a system are the same as they would be for an ideal gas. It was called the κT line. Various substances and models have been studied with the use of the multi-parameter equations of states, implemented in REFPROP (Lemmon, E. W.; Bell, I. H.; Huber, M. L.; McLinden, M. O. NIST standard reference database 23: Reference fluid thermodynamic and transport properties-REFPROP, version 10.0 (National Institute of Standards and Technology, 2018)), and numerical simulations, respectively. It is shown that in the reduced variables, all κT lines can be described by the same relation following from the van der Waals equation. This similarity appears to be valid even for the systems with non-straight Zeno lines. Deviations within ∼5% are observed only near the binodals.