The lead removal evolution from hazardous waste cathode ray tube funnel glass under enhancement of red mud melting and synthesizing value-added glass-ceramics via reutilization of silicate resources

Abstract

Waste CRT funnel glass (FG) is a typical hazardous waste produced by the electronics industry that contains toxic lead oxide, red mud (RM) is the first waste produced during alumina production. Both of these are extremely difficult to reuse. Here, we report a method to control FG waste, in which RM was used to enhance the removal of Pb from FG via a vacuum thermal process. The removed residual glass was utilized to create glass-ceramics. The results showed that RM can enhance the lead removal from waste CRT funnel glass by the vacuum thermal process. When 30% RM was added, the removal rate reached 98.54%. A significant mechanism of enhancing delead is investigated by a Fourier transform infrared (FTIR) spectrometer and X-ray photoelectron spectroscopy (XPS). The results showed that the -Pb-O-Si-O- network structure was broken by the free calcium ions of RM. Afterward, valuable glass-ceramics with tetragonal-KAlSi2O6 and triclinic-CaSiO3 crystals were synthesized using the residual glass. The Pb, Ba, Cr, and Cu leaching concentrations of the glass-ceramics were well below the regulatory limit (5 mg/L) of the CA-EPA, as measured by the toxicity characteristic leaching procedure (TCLP) test. Overall, the results indicated that RM enhanced the removal of lead during the vacuum thermal process. The synthesis of value-added glass-ceramics reutilized silicate resources from waste cathode ray tube (CRT) funnel glass and RM.