Abstract
Calculating accurate air-sea fluxes for polychlorinated biphenyls (PCBs) is an essential condition for evaluating their transport in the atmosphere. A three-dimensional hydrodynamic-ecosystem-PCB coupled model was developed for the northwestern Pacific Ocean to assess the air-sea fluxes of four PCBs and examine the influences of ocean currents on the fluxes. The model revealed a fine structure in the air-sea flux that is sensitive to the Kuroshio, a western boundary current with a high surface speed. Intense downward and upward fluxes (-23.6 to 44.75 ng m-2 d-1 for ∑4PCBs) can be found in the Kuroshio region south of Japan and the Kuroshio Extension east of Japan, respectively. In strong (weak) current regions, it takes ∼4 and ∼1 days (1-3 and 3-12 days) for dissolved PCBs to reach an equilibrium in scenarios where only air-sea exchange or only ocean advection is considered, respectively. In strong current regions, the ocean advection has a shorter response time than the air-sea exchange, indicating that dissolved PCBs from upstream carried by strong current can easily change the downstream concentration by disrupting the equilibrium with original air-sea exchange and induce new air-sea fluxes there. Therefore, strong western boundary currents should be correctly considered in future atmospheric transport models for PCBs.
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