Abstract
The kinetics of the precipitation of Co from a supersaturated solid solution of Cu-0.95 at. pct Co was investigated by isochronal annealing applying differential scanning calorimetry (DSC) with heating rates in the range 5 to 20 K min–1. The corresponding microstructural evolution was investigated by high-resolution transmission electron microscopy (HRTEM) in combination with electron energy loss spectroscopy (EELS). Upon isochronal annealing, spherical Co precipitates of fcc crystal structure form. Kinetic analysis by fitting of a modular phase transformation model to, simultaneously, all DSC curves of variable heating rate measured for Cu-0.95 at. pct Co showed that the precipitation-process mechanism can be described within the framework of this general phase transformation model by continuous nucleation and diffusion-controlled growth. By introducing additional microstructural information (here, the precipitate-particle density), for the first time, values for the separate activation energies of nucleation and growth could be deduced from the transformation kinetics.
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