The kinetics of Indonesian galena concentrate leaching in fluorosilicic acid and hydrogen peroxide as its oxidants

Abstract

Lead smelting is known as a lead extraction technique which has negative impact to environment because it produces emissions of dust, SO 2 gas and lead. The leaching is conducted to reduce the smelting’s weaknesses by extracting the lead without damaging the environment. This technique, often called hydrometallurgical lead extraction, uses liquid media to extract the lead and separate it from the elemental sulphur (S 0 ) by filtration. Particle size, slurry density (solid percentage) and acid concentration affect the dissolution of Indonesian galena concentrate with fluorosilicic acid and hydrogen peroxide as oxidants. By means of these reagents, it is expected that the Pb extraction process from galena concentrate resulted from flotation of sulfide ore can be carried out at low temperatures and lead recovery can be accomplished from the leach solution by electrowining. Studying galena leaching kinetics is required to perform galena leaching with high Pb extraction percentages. Two kinetics models are commonly used to study leaching kinetics, namely shrinking core model (SCM) and shrinking particle model (SPM). These models are used to determine the mechanism which controls leach reaction and reaction rate constant or diffusion constant of the reacting species. Total plotting of sulfide fraction dissolves with time adjusted to the existing mathematical model, and fitting the curve from the dummy model to the experimental data, are two techniques that are utilized to obtain the best kinetics model which important in controlling the leaching reaction rate. Applying the Arrhenius equation, the relation of the reaction rate constant or the diffusion constant and the temperature is determined to calculate the leaching activation energy. The result from kinetics analysis showed that the leaching of Indonesian galena concentrate in fluorosilicic acid with hydrogen peroxide as oxidants followed the shrinking core model with diffusion through porous solid product layer as the reaction controller with activation energy of 45.81 kJ/mol or 10.91 kcal/mol.