Abstract
The kinetics of the Cu++-catalyzed reduction of CrVI by H2 in aqueous perchlorate solutions have been investigated between 160° and 200 °C. The mechanism proposed to account for the kinetics gives rise to a rate law of the form[Formula: see text]where[Formula: see text]As a consequence of these studies an important anomaly between the previously published rate law for dichromate reduction and a more recent kinetic study of the cupric-perchlorate-catalyzed hydrogen–oxygen recombination has been resolved.
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