Abstract
D is found to have a higher trans influence than H, as reflected in /sup 1/J(Pt,P) and /sup 1/J(Pt,C) coupling constants in trans-(HPt(PEt/sub 3/)/sub 2/L)/sup +/ (L = /sup 13/CO or PEt/sub 3/) and the PtD analogues. The isotopic effect on trans ligand labilization is also discussed in the case of (IrH/sub 2/(Me/sub 2/CO)/sub 2/(PPh/sub 3/)/sub 2/)/sup +/. Molecular H/sub 2/ (D/sub 2/) complexes are proposed as intermediates in the deuteration of the iridium complex.
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