The investigation of quenching conditions for the analysis of total organic halogen, aliphatic and aromatic halogenated disinfection byproducts formed from chlor(am)ination

Abstract

Total organic halogen (TOX) is used to describe total amount of halogenated DBPs. Typically, once a chlor(am)inated water sample is collected, it is necessary to add a quenching agent to quench the residual disinfectant so that further reactions to form more DBPs during the holding time can be prevented. In this study, we evaluated the effects of four quenching agents: ammonium chloride (NH4Cl), ascorbic acid, sodium sulfite (Na2SO3), and sodium thiosulfate (Na2S2O3) on the decomposition of TOX, aliphatic and aromatic halogenated DBPs under various quenching conditions (quenching time, pH, quenching ratio, temperature). The results showed that ascorbic acid had the least impact on TOX. Ascorbic acid appeared to be the most suitable quenching agent for aliphatic halogenated DBPs, especially since it could preserve more haloacetonitriles than other quenching agents. Both ascorbic acid and Na2SO3 could be used for the analysis of aromatic halogenated DBPs. The lower pH (pH 6.0), not excessive quenching agents and lower temperature (4 ºC) were all conducive to the preservation of TOX and halogenated DBPs. Importantly, unknown TOX (UTOX) also contained significantly toxic components. It was also found that addition of quenching agents might lead to underestimation of UTOX by researchers. SynopsisThe quenching agents and quenching conditions for the analysis of total organic halogen, aliphatic and aromatic halogenated DBPs formed from chlor(am)ination were investigated.