Abstract
The internal optic modes of BrO3− and ClO3− ions are studied in a series of NaClO3/NaBrO3 mixed crystals over the entire relative concentration range. Raman spectra and near-normal incidence infrared reflectivity spectra of single mixed crystals and Raman spectra of microcrystalline mixed crystal powders are presented and discussed. Mode mixing of the ν1 and ν3 modes of BrO3− was studied as a function of concentration, and a near accidental degeneracy of ν1 and ν3 was noted in the high dilution limit of matrix isolated BrO3− in a host NaClO3 crystal.
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