Abstract
The remarkably reversible thermochromic luminescence behavior and the rare nonlinear optical (NLO) properties of the [Ag55(MoO4)6(C Created by potrace 1.16, written by Peter Selinger 2001-2019 ]]> CtBu)24(CH3COO)18(CH3COO)]·2H2O ({Ag55Mo6} for short) nanocluster reported were investigated experimentally. The important contributions of Ag+, CC− ions and MoO42− groups to the NLO properties were proved by further density functional theory (DFT) calculations.
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