Abstract
A continuous flow apparatus is set up to study the enzymatic interesterification of palm oil by stearic acid in supercritical carbon dioxide. Domestic edible palm oil is mixed with stearic acid and loaded to a saturation tank in which the oil is extracted by supercritical carbon dioxide. The current of the extraction solution bubbled from the saturation tank is delivered to an enzyme-packed column. In this study, five triglycerides (POP, POS, POO, OOO, and SOO) and two free fatty acids (stearic acid and palmic acid) are selected as indicators to monitor the interesterification. The results show that the Mucor miehei dominantly catalyzes the interesterifications of POP+S«POS and POO+S«SOO when the stearic acid content in the extraction solution is abundant. A very limited amount of SOS is also irregularly found in the product samples. POS and SOO are rarely produced when the loaded stearic acid is completely elutriated, and the weight fraction of POO is significantly increased by the depletion of POP. It is presumed that the palmitoyl group in the 1,3 position is substituted much more readily, and that the stearic acid is a reactive acyl donor for the interesterification in supercritical carbon dioxide when catalyzed by Mucor miehei. That large amounts of palmic acid are found in the transesterified oil confirms this presumption.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.