Abstract

AbstractAlthough substitution of chlorine usually occurs in the interaction of chloranil with aliphatic amines, solutions of chloranil in pure triethylamine yield a product which appears to be a salt, the anion of which is the free radical semiquinone ion derived from chloranil. In acetone solution this salt decomposes to yield 2,3,5‐trichloro‐6‐(2′‐diethylaminovinyl)‐p‐benzoquinone.

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