The interaction laws of atmospheric heavy metal ions and water-soluble organic compounds in PM2.5 based on the excitation-emission matrix fluorescence spectroscopy

Abstract

The excitation-emission matrix (EEM) fluorescence spectroscopy was used to characterize the fluorescence properties of water-soluble organic compounds (WSOCs) in PM2.5 coupled with parallel factor analysis (PARAFAC). Three main components of WSOCs were extracted from PM2.5, i.e., humic-like (fulvic acid-like and humic acid-like) substances (HULIS), and soluble microbial by-product-like or aromatic protein-like, respectively. A fluorescence quenching experiment was designed to systematically analyze the interaction laws of atmospheric heavy metal ions and WSOCs in PM2.5. Our study revealed HULIS, especially the humic acid-like substances, might be principal substances binding with metal ions and the strength of interactions was related to the types and concentrations of metal ions. Furthermore, EEM was a powerful tool to understand the interaction laws of atmospheric heavy metal ions and WSOCs in PM2.5. This work implied that the interactions of atmospheric heavy metal ions and WSOCs might directly or indirectly play a significant role in atmospheric environment and public health.