The insight study of SnO pico size particles in an ethanol-water system followed by its biosensing application

Abstract

Pico sized Stannous oxide particles (SnO PPs) were synthesized in an ethanol-water solvent system on the surface of nitrogen doped graphene oxide (GO). The highly conductive support was a combination of dual interactions between 4-aminomethylbenzylamine (AMBA) and GO. The oppositely positioned –NH2 linkers of the AMBA were covalently incorporated into the GO matrix through condensation reaction followed by the strong π – π stacking interactions between aromatic rings of AMBA and GO. The change in the local chemical environment of GO via dual interactions provided a suitable atmosphere for the growth and dispersion of SnO PPs on GO-AMBA surface. The possible mechanism for the formation of SnO in an ethanol-water solvent system was evaluated. Furthermore, a light was shed on the factors responsible for the pico size of SnO particles synthesis along with its phenomenal distribution on the GO-AMBA surface. The catalyst containing SnO PPs was deployed as a biosensor for the detection of ascorbic acid (AA) for the very first time. A very wide linear range of 5.0 × 10−5–7.0 × 10−3 M, limit of detection (LOD) of 1.19 × 10−5 M along with excellent practical feasibility, storage stability, repeatability and selectivity towards AA electrooxidation showed the excellent synergy between nitrogen-rich GO surface and SnO PPs. The sensitivity (885.54 µAmM−1cm−2) of the catalyst was the most attractive feature, as it was obtained in the presence of 5 and 2-fold higher concentration of UA and DA interfering species respectively.