Abstract
Whereas the soluble reagent indium(I) trifluoromethanesulfonate, InOTf, does not appear to react rapidly with chlorinated solvents, the crown ether ligated compounds [In(18-crown-6)][OTf] and [In(dibenzo-18-crown-6)][OTf] react rapidly with CH 2Cl 2 and CHCl 3 to produce the corresponding C–Cl insertion products. The structural features and the formation of the new indium-containing products are rationalized.
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