Abstract

The vibrational IR and Raman spectra of tetrachlorophthalic anhydride, tetrachlorophthalimide, N- d-tetrachlorophthalimide and potassium tetrachlorophthalimide have been measured for polycrystalline samples and the observed bands have been assigned tentatively by comparison with those of tetrahydro-compounds. To confirm the assignments, a normal coordinate analysis has been carried out on an assumption of the valence force field. The CO stretching modes of the OCXCO resonating system have been discussed in terms of the observed frequencies and the calculated force constants.

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