Abstract
Infra-red spectra have been recorded for silyl fluoride and silyl fluoride-d 3 at a resolution of circa 0·3 cm-1. Rotational structure has been observed for parallel fundamentals in both molecules, and for all perpendicular fundamentals. In both SiH3F and SiD3F the A 1 and E species deformation modes interact strongly via a Coriolis perturbation; this has been analysed, and the band origin of v 5 for SiH3F is reassigned. A hybrid-orbital force field based on the experimental data is also reported.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
