Abstract
This laboratory experiment investigated changes in the dissolution of North Carolina phosphate rock and NaHCO3-soluble P arising from the addition of goethite (�-FeOOH) to soil. Increasing goethite in the soil increased the amount of phosphate rock (PR) dissolution as measured by the increase in exchangeable Ca (�Ca) values. Increased dissolution was, however, associated with decreased NaHCO3- soluble P due to P retention by goethite. The proportion of P dissolved from PR that was soluble in 0.5 M NaHCO3 solution decreased with contact period and with increased goethite. The increase in exchangeable Ca (�Ca) was a better indicator of the extent of PR dissolution in goethite-containing soils than NaHCO3-soluble P.
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