Abstract
The two-step reduction of Zn 2+ ions at the dropping mercury electrode in 2, 3, and 4 mol dm -3 NaClO4 with the addition of tert-butanol, using the impedance method in wide potential and frequency ranges was examined. An inhibiting influence of tert-butanol is shown in the used experimental systems, which increases with the rise of the base electrolytes concentration. This effect caused by NaClO4 concen- tration change is probably linked with the electrodes surface and the Zn + aquaion composition change. (doi: 10.5562/cca1726)
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