Abstract

The extremely low electronic conductivity, slow ion diffusion kinetics, and the Jahn–Teller effect of LiMnPO4 limit its electrochemical performance. In this work, a nutty-cake structural C–LiMn1−xFexPO4–LiFePO4 cathode material is synthesized by hydrothermal method and further calcined at different temperatures. The influence of calcination temperature on the electrochemical behavior is investigated by X-ray diffractometer, scanning electron microscope, field-emission high-resolution transmission electron microscope, energy-dispersive X-ray spectroscopy, electrochemical impedance spectroscopy and charge–discharge tests. And the performance of C–LiMn1−xFexPO4–LiFePO4 materials has a relationship with its crystal structure. The well-crystallized Sample-600 calcined at 600 °C shows the smallest charge transfer resistance, the largest lithium ion diffusion coefficient (DLi) and the best cycling stability. The discharge capacity of Sample-600 holds around 112 mAh g−1 after the 3rd cycle at 0.1 C rate. The performances improvement of C–LiMn1−xFexPO4–LiFePO4 material can be mainly attributed to the iron diffusion from the LiFePO4 core to the outer LiMnPO4 layer under appropriate calcination temperature.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call