Abstract
Abstract The influence of the TCNQ0 content defined as x = [TCNQ0]/[TCNQ−] on the properties of TCNQ complex salts containing S+ in the main chains are presented and discussed. Both the specific resistivity and the thermal activation energy of the conductivity had a minimum for x close to 0.9. The decrease of resistivity with an increase in the x ratio is explained by a decrease in the dimer concentration. The increase of resistivity for x increasing above 0.9 is explained by the formation of crystalline TCNQ0 domains. The discussion is based on ESR, optic absorption, and crystallinity data.
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More From: Journal of Macromolecular Science: Part A - Chemistry
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