Abstract

Differences on carbon content and chemical bonds in a-Si1−xCx:H were observed and analyzed in carbon rich and silicon rich films, deposited by plasma enhanced chemical vapor deposition from mixtures of silane and methane. The influence of the radio frequency low power density regime on the film’s properties was investigated. The content of Si, C, and H in the solid phase was obtained by Rutherford back scattering and forward recoil spectrometry. The bondings were analyzed by Fourier transform infrared spectroscopy. Quantitative analysis on the film’s chemical composition was performed combining the vibrational spectra with the stoichiometry data. The results showed that under “silane starving plasma” conditions, a carbon content as high as 70 at. % is achieved and the main carbon bonds are tetragonal C–H, C–H2, and Si–C.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.