The influence of scale/metal interface characteristics on the oxidation behaviour of iron at elevated temperatures

Abstract

The oxidation kinetics of cold-rolled Remko iron coupons in purified oxygen at atmospheric pressure in the temperature range 973–1173K and the morphologies of both oxide scales and subtrate surfaces were studied using thermogravimetric, metallographic and scanning electron-microscope techniques. Parabolic oxidation rate constants were found to decrease after initial varying periods of constancy, an effect believed to be due to void formation at the wüstite/iron interfaces by the coalescence of vacancies. The observed subsequent recoveries of the values of the rate constants were considered to be due to an increase in oxide growth stresses to values large enough to cause appreciable plastic flow of oxide, thereby decreasing the number of interfacial voids. The extent of the deviations from the initial values of the rate constants decreased as the oxidation temperature was increased and this was considered to be due to the enhanced plasticity of the scale and increased rate of stress generation which favoured the elimination of the interfacial voids. In the temperature range 973–1073K, there were periods in which logarithmic growth relationships were observed, the mechanism being similar to that suggested by Evans, and involving a continuous increase in the number of interfacial voids.