Abstract

The purpose of this study was to determine how magnesium in seawater influences the corrosion behaviour of freely corroding steel. This was done by studying if Mg(OH) 2 is formed and if calcite and aragonite differ in their protective properties. No Mg(OH) 2 was detected after immersion of steel in a Mg 2+-containing artificial seawater. Magnesium seems to influence the corrosion behaviour of freely corroding steel by causing calcium carbonate to precipitate as aragonite. Aragonite is more effective in covering the surface than calcite and is therefore more functional in preventing oxygen from reaching the steel surface, thereby lowering the corrosion rate.

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