The influence of mechanical activation on the electrical properties of Ba0.77Sr0.23TiO3 ceramics

Abstract

Ferroelectric barium strontium titanate (Ba0.77Sr0.23TiO3), BST, was prepared by solid-state reactions using as the starting compounds powder of barium carbonate (BaCO3), strontium carbonate (SrCO3) and titanium dioxide (TiO2–anatase). Non-activated mixtures and mixtures mechanically activated in a high-energy planetary ball mill (0, 5, 10, 20, 40, 80 and 120min) were sintered at 1100, 1200, 1300 and 1400°C for 2h in air atmosphere. Defects and the effect of the beginning of the sintering process on the microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements (loss tangent and resistivity as the function of frequency XC=f(logν)) were performed for ceramics sintered at 1400°C for 2h. It has been found that mechanical activation can reduce the sintering temperature by around 100°C, which leads to significant energy savings. Furthermore, activated for 80min and sintered at 1400°C for 2h exhibit the largest density values and have about 36% lower dielectric loss at a frequency of 1kHz and about 57% at a frequency of 10kHz than the samples obtained from the initial non-activated powder sintered under the same conditions.