Abstract

In blackcurrant juice powders made using freeze-, vacuum-, and spray-drying methods, 19 polyphenolic compounds were identified: anthocyanins (6), (+)-catechin, flavonols (8), and phenolic acids (4). The highest content of identified polyphenols was noted after vacuum drying at 90 °C, which was connected with the thermally induced release of (+)-catechin. Drying at this temperature also increased the formation of the Maillard reaction/caramelization product, hydroxymethyl-l-furfural, when inulin was added. The higher the vacuum drying temperature was, the stronger the degradation of anthocyanins was. Inulin was a better protectant of anthocyanins than maltodextrin, except during vacuum drying at 90 °C, which probably triggered inulin’s participation in the formation of hydroxymethyl-l-furfural (HMF), thus limiting its capability to protect anthocyanins. Flavonols and phenolic acids were best retained after vacuum drying at 50 °C. Carrier selection affected only slightly, whereas carrier concentration did not affect, the content of flavonols and phenolic acids. The quality of fruit juice powders should be considered taking into account a broad spectrum of factors, including the initial composition of the material subjected to drying, the drying parameters, the carrier type and concentration, and the interactions that occur during the thermal treatment of fruit juices.

Highlights

  • Blackcurrant (Ribes nigrum L.) is a fruit shrub from the Grossulariaceae family originating from the European and Asian areas situated in the temperate climate zone [1]

  • 19 polyphenolic compounds were identified in blackcurrant juice powders, among which anthocyanins (6) were the dominant group followed by flavan-3-ol (1), flavonols (8), and phenolic acids (4)

  • The sum of all identified polyphenols was significantly higher after vacuum drying at 90 ◦ C when compared to the rest of the applied methods, which was connected with the thermally induced release of (+)-catechin during vacuum drying at 90 ◦ C

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Summary

Introduction

Blackcurrant (Ribes nigrum L.) is a fruit shrub from the Grossulariaceae family originating from the European and Asian areas situated in the temperate climate zone [1]. In 2016, the global blackcurrant production was 655.03 thousand tons, with the top producers being Russia (60.3%), Poland (25.4%), Ukraine (3.7%) and Germany (2.1%) [2]. There has recently been an overproduction of blackcurrant, so its production is becoming less and less profitable, and the fruit is not fully utilized. Blackcurrant is a very valuable material thanks to its high health-promoting potential, which results from the presence of bioactive compounds, including high amounts of vitamin C and polyphenols [3]. Besides many healthy chemical compounds, blackcurrant contains a lot of dietary fiber, such as pectin [4], and has a Molecules 2019, 24, 4167; doi:10.3390/molecules24224167 www.mdpi.com/journal/molecules

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