Abstract
The kinetics of methanol chemisorption on a platinized electrode at +0.5 V and the influence of halide ions thereon has been studied. It was shown that the rate of adsorption decreased in the presence of halide ions during simultaneous adsorption. When halide ions were added to the solution, previously adsorbed methanol was completely removed from the surface only in the case of chloride ions. The adsorbed intermediates react with bromide and iodide ions and the products of the reaction remain strongly bound to the surface, being only partially oxidized at +1.2 V.
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