The influence of electron confinement, quantum size effects, and film morphology on the dispersion and the damping of plasmonic modes in Ag and Au thin films

Abstract

Plasmons are collective longitudinal modes of charge fluctuation in metal samples excited by an external electric field. Surface plasmons (SPs) are waves that propagate along the surface of a conductor. SPs find applications in magneto-optic data storage, optics, microscopy, and catalysis.The investigation of SPs in silver and gold is relevant as these materials are extensively used in plasmonics. The theoretical approach for calculating plasmon modes in noble metals is complicated by the existence of localized d electrons near the Fermi level. Nevertheless, recent calculations based on linear response theory and time-dependent local density approximation adequately describe the dispersion and damping of SPs in noble metals.Furthermore, in thin films the electronic response is influenced by electron quantum confinement. Confined electrons modify the dynamical screening processes at the film/substrate interface by introducing novel properties with potential applications. The presence of quantum well states in the Ag and Au overlayer affects both the dispersion relation of SP frequency and the damping processes of the SP.Recent calculations indicate the emergence of acoustic surface plasmons (ASP) in Ag thin films exhibiting quantum well states. The slope of the dispersion of ASP decreases with film thickness.High-resolution electron energy loss spectroscopy (HREELS) is the main experimental technique for investigating collective electronic excitations, with adequate resolution in both the energy and momentum domains to investigate surface modes.Herein we review on recent progress of research on collective electronic excitations in Ag and Au films deposited on single-crystal substrates.