Abstract

The phase relations within the system Bi 2O 3PbOrOCaOCuO including Ag has been studied with emphasis on the superconducting phases (Bi,Pb) 2Sr 2Ca 2Cu 3O 10 (2223 phase) and Bi 2Sr 2CaCu 2O 8 (2212 phase). The onset temperatures of the peritectic melting of 2223 and 2212 were observed to be decreased by about 20–30 °C when Ag is present. In addition, the solid solubility of Sr in 2212 and Pb in 2223 is affected by Ag.

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