Abstract

The synthesis, spectroscopic characterization, electrochemistry and photophysical measurements of three 2-methoxyphenylfullerene derivatives are described and their properties compared. Cyclic and Osteryoung square-wave voltammetry studies indicate that the pyrazolino[60]fullerene shows improved electron affinity in comparison to the parent C60. Preliminary photophysical studies suggest the occurrence of an electron transfer process.

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