Abstract

In this paper, the high-accuracy ion mobility coefficient based on the Chapman–Enskog approximation to the solution of the Boltzmann equation for low pressure radio frequency plasma discharges is presented. We employ two-dimensional fluid simulations of the argon filled axisymmetric reactor, where the effect of new ion-kinetics-based fluid closure is compared to theoretical expressions and experimental data. The spatial profiles of plasma composition in the low pressure radio frequency capacitively coupled plasma are presented, which includes the metastable reactions in the simulation. Moreover, inelastic collision integrals terms, due to charge exchange inelastic collisions between ions and neutral species, have been also considered. A Monte Carlo simulation of kinetic ion energy distribution of impinging on the radio frequency powered electrode provides a measure of accuracy of the new transport model. From our simulation, the results that mirror the influence of ion mobility coefficient obtained by the Chapman–Enskog method on plasma physical quantities under different pressures, frequencies, and electrode gaps is in good agreement with experimental measurement results and theoretical expressions.

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