The hygroscopic properties of biomass burning aerosol from Eucalyptus and cow dung under different combustion conditions

Abstract

Aerosols hygroscopic growth is of current interest due to its effect on atmospheric light scattering and extinction. Knowledge of hygroscopic properties is essential for predicting the effect of aerosol on cloud formation, regional visibility, climate impact, and lung deposition. Previous studies have used surrogate components of complex aerosol; and the application to complex multi-component aerosol like biomass burning aerosol is limited. We report aerosol hygroscopicity parameter of biomass burning aerosol derived from Eucalyptus and cow dung in a humidified smog chamber using two techniques: (1) measuring extinction hygroscopic enhancement factor f(RH) of aerosol using a cavity ring down spectrometer and deriving the hygroscopicity parameter using empirical equations and (2) directly using a Cloud Condensation Nuclei Counter (CCNC). Based on repeated measurements of the same fuel under different burning conditions, quantified by the modified combustion efficiency (MCE), we found that aerosol hygroscopicity depends on both fuel types and to some extent on burning conditions. For similar MCE, cow dung has a consistently larger value of hygroscopicity compared to Eucalyptus. Hygroscopicity measurements ranged from 0.024 to 0.577 for MCE measurements that ranged from 0.73 to 0.99. Specifically, sub-saturated hygroscopicity parameter values for cow dung are 0.024–0.131 and Eucalyptus are 0.012–0.300, while supersaturated hygroscopicity parameter values for cow dung are 0.071–0.577 and Eucalyptus are 0.021–0.494. There is a clear increase in hygroscopicity with increasing MCE for supersaturated cow dung measurements using CCNC but the dependence of kappa on MCE is generally inconclusive.