Abstract
The hydration products of Portland cement pastes cured using water containing tin(II) chloride have been compared with those using distilled water. In the latter case, the expected products—portlandite, ettringite and calcite—were observed. The X-ray diffraction patterns of the cement pastes cured in the presence of tin(II) chloride showed several additional peaks that have been attributed to the formation of calcium hydroxo-stannate, CaSn(OH)6, and Friedel's salt (tetracalcium aluminate dichloride-10-hydrate), Ca3Al2O6·CaCl2·10H2O. The amount of portlandite formed was reduced in the presence of tin(II) chloride. Calcium hydroxo-stannate contains tin in the +IV oxidation state and equations are presented to account for the oxidation of Sn(II) to Sn(IV) preceding the formation of CaSn(OH)6 and Friedel's salt.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
